ORGANIC CHEMISTRY II

Introduction to Alkanols and Nomenclature

By the end of the lesson, the learner should be able to:
Define alkanols and identify functional group
- Apply nomenclature rules for alkanols
- Draw structural formulae of simple alkanols
- Compare alkanols with corresponding alkanes

Q/A: Review alkanes, alkenes from Form 3
- Study functional group -OH concept
- Practice naming alkanols using IUPAC rules
- Complete Table 6.2 - alkanol structures

Molecular models, Table 6.1 and 6.2, alkanol structure charts, student books

KLB Secondary Chemistry Form 4, Pages 167-170

ORGANIC CHEMISTRY II

Isomerism in Alkanols
Laboratory Preparation of Ethanol

By the end of the lesson, the learner should be able to:
Explain positional and chain isomerism
- Draw isomers of given alkanols
- Name different isomeric forms
- Classify isomers as primary, secondary, or tertiary

Study positional isomerism examples (propan-1-ol vs propan-2-ol)
- Practice drawing chain isomers
- Exercises on isomer identification and naming
- Discussion on structural differences

Isomer structure charts, molecular models, practice worksheets, student books
Sugar, yeast, warm water, conical flask, delivery tube, lime water, thermometer

KLB Secondary Chemistry Form 4, Pages 170-171

ORGANIC CHEMISTRY II

Industrial Preparation and Physical Properties
Chemical Properties of Alkanols I
Chemical Properties of Alkanols II
Uses of Alkanols and Health Effects
Introduction to Alkanoic Acids

By the end of the lesson, the learner should be able to:
Explain hydration of ethene method
- Compare laboratory and industrial methods
- Analyze physical properties of alkanols
- Relate properties to molecular structure
Investigate oxidation and esterification reactions
- Test oxidizing agents on ethanol
- Prepare esters from alkanols
- Explain dehydration reactions

Study ethene hydration using phosphoric acid catalyst
- Compare fermentation vs industrial methods
- Analyze Table 6.3 - physical properties
- Discussion on hydrogen bonding effects
Complete Experiment 6.2: Test with acidified K₂Cr₂O₇ and KMnO₄
- Observe color changes
- Esterification with ethanoic acid
- Study dehydration conditions

Table 6.3, industrial process diagrams, ethene structure models, property comparison charts
Ethanol, sodium metal, universal indicator, concentrated H₂SO₄, ethanoic acid, test tubes
Acidified potassium chromate/manganate, ethanoic acid, concentrated H₂SO₄, heating apparatus
Charts showing alkanol uses, health impact data, methylated spirit samples, discussion materials
Alkanoic acid structure charts, Table 6.5 and 6.6, molecular models, student books

KLB Secondary Chemistry Form 4, Pages 171-173
KLB Secondary Chemistry Form 4, Pages 173-176

ORGANIC CHEMISTRY II

Laboratory Preparation of Ethanoic Acid

By the end of the lesson, the learner should be able to:
Prepare ethanoic acid by oxidation
- Write equations for preparation
- Set up oxidation apparatus
- Identify product by testing

Experiment 6.3: Oxidize ethanol using acidified KMnO₄
- Set up heating and distillation apparatus
- Collect distillate at 118°C
- Test product properties

Ethanol, KMnO₄, concentrated H₂SO₄, distillation apparatus, thermometer, round-bottom flask

KLB Secondary Chemistry Form 4, Pages 179-180

ORGANIC CHEMISTRY II

Physical and Chemical Properties of Alkanoic Acids

By the end of the lesson, the learner should be able to:
Investigate chemical reactions of ethanoic acid
- Test with various reagents
- Write chemical equations
- Analyze acid strength

Experiment following Table 6.8: Test ethanoic acid with indicators, metals, carbonates, bases
- Record observations
- Write equations
- Discuss weak acid behavior

2M ethanoic acid, universal indicator, Mg strip, Na₂CO₃, NaOH, phenolphthalein, test tubes

KLB Secondary Chemistry Form 4, Pages 180-182

ORGANIC CHEMISTRY II

Esterification and Uses of Alkanoic Acids
Introduction to Detergents and Soap Preparation

By the end of the lesson, the learner should be able to:
Explain ester formation process
- Write esterification equations
- State uses of alkanoic acids
- Prepare simple esters

Complete esterification experiments
- Study concentrated H₂SO₄ as catalyst
- Write general esterification equation
- Discuss applications in food, drugs, synthetic fibres

Ethanoic acid, ethanol, concentrated H₂SO₄, test tubes, heating apparatus, cold water
Castor oil, 4M NaOH, NaCl, evaporating dish, water bath, stirring rod, filter paper

KLB Secondary Chemistry Form 4, Pages 182-183

ORGANIC CHEMISTRY II

Mode of Action of Soap and Hard Water Effects
Soapless Detergents and Environmental Effects

By the end of the lesson, the learner should be able to:
Explain soap molecule structure
- Describe cleaning mechanism
- Investigate hard water effects
- Compare soap performance in different waters
Explain soapless detergent preparation
- Compare advantages/disadvantages
- Discuss environmental impact
- Analyze pollution effects

Study hydrophobic and hydrophilic ends
- Demonstrate micelle formation
- Test soap in distilled vs hard water
- Observe scum formation
- Write precipitation equations
Study alkylbenzene sulphonate preparation
- Compare Table 6.9 - soap vs soapless
- Discussion on eutrophication and biodegradability
- Environmental awareness

Soap samples, distilled water, hard water (CaCl₂/MgSO₄ solutions), test tubes, demonstration materials
Flow charts of detergent manufacture, Table 6.9, environmental impact data, sample detergents

KLB Secondary Chemistry Form 4, Pages 186-188
KLB Secondary Chemistry Form 4, Pages 188-191

ORGANIC CHEMISTRY II

Introduction to Polymers and Addition Polymerization

By the end of the lesson, the learner should be able to:
Define polymers, monomers, and polymerization
- Explain addition polymerization
- Draw polymer structures
- Calculate polymer properties

Study polymer concept and terminology
- Practice drawing addition polymers from monomers
- Examples: polyethene, polypropene, PVC
- Calculate molecular masses

Polymer samples, monomer structure charts, molecular models, calculators, polymer formation diagrams

KLB Secondary Chemistry Form 4, Pages 191-195

ORGANIC CHEMISTRY II

Addition Polymers - Types and Properties

By the end of the lesson, the learner should be able to:
Identify different addition polymers
- Draw structures from monomers
- Name common polymers
- Relate structure to properties

Study polystyrene, PTFE, perspex formation
- Practice identifying monomers from polymer structures
- Work through polymer calculation examples
- Properties analysis

Various polymer samples, structure identification exercises, calculation worksheets, Table 6.10

KLB Secondary Chemistry Form 4, Pages 195-197

ORGANIC CHEMISTRY II

Condensation Polymerization and Natural Polymers
Polymer Properties and Applications

By the end of the lesson, the learner should be able to:
Explain condensation polymerization
- Compare with addition polymerization
- Study natural polymers
- Analyze nylon formation

Study nylon 6,6 formation from diamine and dioic acid
- Natural polymers: starch, protein, rubber
- Vulcanization process
- Compare synthetic vs natural

Nylon samples, rubber samples, condensation reaction diagrams, natural polymer examples
Table 6.10, polymer application samples, environmental impact studies, product examples

KLB Secondary Chemistry Form 4, Pages 197-200

ORGANIC CHEMISTRY II

Comprehensive Problem Solving and Integration
Introduction to Organic Chemistry and Hydrocarbons

By the end of the lesson, the learner should be able to:
Solve complex problems involving alkanols and acids
- Apply knowledge to practical situations
- Integrate polymer concepts
- Practice examination questions
Define organic chemistry and hydrocarbons
Explain why carbon forms many compounds
Classify hydrocarbons into alkanes, alkenes, and alkynes
Identify the bonding in carbon compounds

Worked examples on organic synthesis
- Problem-solving on isomers, reactions, polymers
- Integration of all unit concepts
- Practice examination-style questions
Teacher exposition: Definition of organic chemistry. Discussion: Unique properties of carbon - tetravalency, catenation, multiple bonding. Q/A: Examples of hydrocarbons in daily life. Introduction to three main groups of hydrocarbons.

Comprehensive problem sets, past examination papers, calculators, organic chemistry summary charts
Carbon models, Hydrocarbon structure charts, Molecular model kits

KLB Secondary Chemistry Form 4, Pages 167-201
KLB Secondary Chemistry Form 3, Pages 86-87

ORGANIC CHEMISTRY I

Sources of Alkanes - Natural Gas, Biogas, and Crude Oil

By the end of the lesson, the learner should be able to:
Identify natural sources of alkanes
Describe composition of natural gas and biogas
Explain crude oil as major source of alkanes
Describe biogas digester and its operation

Discussion: Natural gas composition (80% methane). Explanation: Biogas formation from organic waste decomposition. Teacher demonstration: Biogas digester model/diagram. Q/A: Environmental benefits of biogas production.

Biogas digester model/diagram, Natural gas composition charts, Organic waste samples

KLB Secondary Chemistry Form 3, Pages 86-87

ORGANIC CHEMISTRY I

Fractional Distillation of Crude Oil

By the end of the lesson, the learner should be able to:
Explain fractional distillation process
Perform fractional distillation of crude oil
Identify different fractions and their uses
Relate boiling points to molecular size

Experiment: Fractional distillation of crude oil using improvised column. Collect fractions at different temperatures (120°C intervals up to 350°C). Test fractions for appearance, flammability, and viscosity. Record observations and relate to molecular size.

Crude oil sample, Boiling tubes, High-temperature thermometer, Sand/porcelain chips, Bunsen burner, Test tubes

KLB Secondary Chemistry Form 3, Pages 87-89

ORGANIC CHEMISTRY I

Cracking of Alkanes - Thermal and Catalytic Methods

By the end of the lesson, the learner should be able to:
Define cracking of alkanes
Distinguish between thermal and catalytic cracking
Write equations for cracking reactions
Explain industrial importance of cracking

Teacher exposition: Definition and purpose of cracking. Discussion: Thermal vs catalytic cracking conditions. Worked examples: Cracking equations producing smaller alkanes, alkenes, and hydrogen. Q/A: Industrial applications and hydrogen production.

Cracking process diagrams, Chemical equation charts, Catalyst samples for demonstration

KLB Secondary Chemistry Form 3, Pages 89-90

ORGANIC CHEMISTRY I

Alkane Series and Homologous Series Concept
Nomenclature of Alkanes - Straight Chain and Branched
Isomerism in Alkanes - Structural Isomers

By the end of the lesson, the learner should be able to:
Define homologous series using alkanes
Write molecular formulas for first 10 alkanes
Identify characteristics of homologous series
Apply general formula CₙH₂ₙ₊₂ for alkanes
Define isomerism in alkanes
Draw structural isomers of butane and pentane
Distinguish between chain and positional isomerism
Predict number of isomers for given alkanes

Teacher exposition: Homologous series definition and characteristics. Table completion: Names, molecular formulas, and structures of first 10 alkanes. Discussion: General formula application. Pattern recognition: Gradual change in physical properties.
Teacher exposition: Isomerism definition and types. Practical exercise: Draw all isomers of butane and pentane. Discussion: Physical property differences between isomers. Model building: Use molecular models to show isomeric structures.

Alkane series chart, Molecular formula worksheets, Periodic table
Structural formula charts, IUPAC naming rules poster, Molecular model kits
Molecular model kits, Isomerism charts, Structural formula worksheets

KLB Secondary Chemistry Form 3, Pages 90-92
KLB Secondary Chemistry Form 3, Pages 92-94

ORGANIC CHEMISTRY I

Laboratory Preparation of Methane

By the end of the lesson, the learner should be able to:
Describe laboratory preparation of methane
Perform methane preparation experiment safely
Test physical and chemical properties of methane
Write equation for methane preparation

Experiment: Heat mixture of sodium ethanoate and soda lime. Collect methane gas over water. Tests: Color, smell, combustion, reaction with bromine in dark. Record observations in table format. Safety precautions during gas collection.

Sodium ethanoate, Soda lime, Round-bottomed flask, Gas collection apparatus, Bromine water, Wooden splints

KLB Secondary Chemistry Form 3, Pages 94-96

ORGANIC CHEMISTRY I

Laboratory Preparation of Ethane

By the end of the lesson, the learner should be able to:
Prepare ethane using sodium propanoate and soda lime
Compare preparation methods of methane and ethane
Test properties of ethane gas
Write general equation for alkane preparation

Experiment: Prepare ethane from sodium propanoate and soda lime. Compare with methane preparation method. Carry out similar tests as for methane. Discussion: General pattern for alkane preparation from sodium alkanoates.

Sodium propanoate, Soda lime, Gas collection apparatus, Testing materials

KLB Secondary Chemistry Form 3, Pages 94-96

ORGANIC CHEMISTRY I

Physical Properties of Alkanes

By the end of the lesson, the learner should be able to:
Describe physical properties of alkanes
Explain trends in melting and boiling points
Relate molecular size to physical properties
Compare solubility in different solvents

Data analysis: Study table of physical properties of first 10 alkanes. Graph plotting: Boiling points vs number of carbon atoms. Discussion: Intermolecular forces and property trends. Q/A: Solubility patterns in polar and non-polar solvents.

Physical properties data tables, Graph paper, Calculators, Solubility demonstration materials

KLB Secondary Chemistry Form 3, Pages 96-97

ORGANIC CHEMISTRY I

Chemical Properties of Alkanes - Combustion and Substitution
Uses of Alkanes in Industry and Daily Life
Introduction to Alkenes and Functional Groups

By the end of the lesson, the learner should be able to:
Write equations for complete and incomplete combustion
Explain substitution reactions with halogens
Describe conditions for halogenation reactions
Name halogenated alkane products
Define alkenes and unsaturation
Identify the C=C functional group
Write general formula for alkenes (CₙH₂ₙ)
Compare alkenes with alkanes

Worked examples: Combustion equations for various alkanes. Teacher demonstration: Methane + bromine in sunlight (or simulation). Discussion: Free radical mechanism in substitution. Practice: Write equations for chlorination of methane.
Teacher exposition: Alkenes definition and unsaturation concept. Introduction: C=C double bond as functional group. Table study: First 6 members of alkene series. Comparison: Alkenes vs alkanes - formulas and structures.

Molecular models, Halogenation reaction charts, Chemical equation worksheets
Industrial application charts, Product samples, Environmental impact materials
Alkene series charts, Molecular models showing double bonds, Functional group posters

KLB Secondary Chemistry Form 3, Pages 97-98
KLB Secondary Chemistry Form 3, Pages 100-101

ORGANIC CHEMISTRY I

Nomenclature of Alkenes

By the end of the lesson, the learner should be able to:
Apply IUPAC rules for naming alkenes
Number carbon chains to give lowest numbers to double bonds
Name branched alkenes with substituents
Distinguish position isomers of alkenes

Teacher demonstration: Step-by-step naming of alkenes. Rules application: Longest chain with double bond, numbering from end nearest double bond. Practice exercises: Name various alkene structures. Group work: Complex branched alkenes with substituents.

IUPAC naming charts for alkenes, Structural formula worksheets, Molecular model kits

KLB Secondary Chemistry Form 3, Pages 101-102

ORGANIC CHEMISTRY I

Isomerism in Alkenes - Branching and Positional

By the end of the lesson, the learner should be able to:
Draw structural isomers of alkenes
Distinguish between branching and positional isomerism
Identify geometric isomers in alkenes
Predict isomer numbers for given molecular formulas

Practical exercise: Draw all isomers of butene and pentene. Teacher exposition: Branching vs positional isomerism in alkenes. Model building: Use molecular models for isomer visualization. Discussion: Geometric isomerism introduction (basic level).

Molecular model kits, Isomerism worksheets, Geometric isomer models

KLB Secondary Chemistry Form 3, Pages 102

ORGANIC CHEMISTRY I

Laboratory Preparation of Ethene

By the end of the lesson, the learner should be able to:
Prepare ethene by dehydration of ethanol
Describe role of concentrated sulfuric acid
Set up apparatus safely for ethene preparation
Test physical and chemical properties of ethene

Experiment: Dehydration of ethanol using concentrated H₂SO₄ at 170°C. Use sand bath for controlled heating. Pass gas through NaOH to remove impurities. Tests: Bromine water, acidified KMnO₄, combustion. Safety precautions with concentrated acid.

Ethanol, Concentrated H₂SO₄, Round-bottomed flask, Sand bath, Gas collection apparatus, Testing solutions

KLB Secondary Chemistry Form 3, Pages 102-104

ORGANIC CHEMISTRY I

Alternative Preparation of Ethene and Physical Properties
Chemical Properties of Alkenes - Addition Reactions
Oxidation Reactions of Alkenes and Polymerization

By the end of the lesson, the learner should be able to:
Describe catalytic dehydration using aluminum oxide
Compare different preparation methods
List physical properties of ethene
Explain trends in alkene physical properties
Explain addition reactions due to C=C double bond
Write equations for halogenation of alkenes
Describe hydrogenation and hydrohalogenation
Explain addition mechanism

Demonstration: Alternative method using Al₂O₃ catalyst. Comparison: Acid vs catalytic dehydration methods. Data analysis: Physical properties of alkenes table. Discussion: Property trends with increasing molecular size.
Teacher exposition: Addition reactions definition and mechanism. Worked examples: Ethene + Cl₂, Br₂, HBr, H₂. Discussion: Markovnikov's rule for unsymmetrical addition. Practice: Various addition reaction equations.

Aluminum oxide catalyst, Glass wool, Alternative apparatus setup, Physical properties charts
Addition reaction charts, Mechanism diagrams, Chemical equation worksheets
Oxidizing agents for demonstration, Polymer samples, Polymerization charts, Monomer-polymer models

KLB Secondary Chemistry Form 3, Pages 102-104
KLB Secondary Chemistry Form 3, Pages 105-107

ORGANIC CHEMISTRY I

Tests for Alkenes and Uses

By the end of the lesson, the learner should be able to:
Perform chemical tests to identify alkenes
Use bromine water and KMnO₄ as test reagents
List industrial and domestic uses of alkenes
Explain importance in plastic manufacture

Practical session: Test known alkenes with bromine water and acidified KMnO₄. Observe rapid decolorization compared to alkanes. Discussion: Uses in plastics, ethanol production, fruit ripening, detergents. Assignment: Research alkene applications.

Test alkenes, Bromine water, Acidified KMnO₄, Plastic samples, Uses reference charts

KLB Secondary Chemistry Form 3, Pages 108-109

ORGANIC CHEMISTRY I

Introduction to Alkynes and Triple Bond

By the end of the lesson, the learner should be able to:
Define alkynes and triple bond structure
Write general formula for alkynes (CₙH₂ₙ₋₂)
Identify first members of alkyne series
Compare degree of unsaturation in hydrocarbons

Teacher exposition: Alkynes definition and C≡C triple bond. Table study: First 6 members of alkyne series with structures. Discussion: Degrees of unsaturation - alkanes vs alkenes vs alkynes. Model demonstration: Triple bond representation.

Alkyne series charts, Triple bond molecular models, Unsaturation comparison charts

KLB Secondary Chemistry Form 3, Pages 109-110

ORGANIC CHEMISTRY I

Nomenclature and Isomerism in Alkynes

By the end of the lesson, the learner should be able to:
Apply IUPAC naming rules for alkynes
Name branched alkynes with substituents
Draw structural isomers of alkynes
Identify branching and positional isomerism

Teacher demonstration: Systematic naming of alkynes using -yne suffix. Practice exercises: Name various alkyne structures. Drawing exercise: Isomers of pentyne and hexyne. Group work: Complex branched alkynes with multiple substituents.

IUPAC naming rules for alkynes, Structural formula worksheets, Molecular model kits

KLB Secondary Chemistry Form 3, Pages 110-111

ORGANIC CHEMISTRY I

Laboratory Preparation of Ethyne
Physical and Chemical Properties of Alkynes
Addition Reactions of Alkynes and Chemical Tests

By the end of the lesson, the learner should be able to:
Prepare ethyne from calcium carbide and water
Set up gas collection apparatus safely
Test physical and chemical properties of ethyne
Write equation for ethyne preparation
Describe physical properties of alkynes
Compare alkyne properties with alkenes and alkanes
Write combustion equations for alkynes
Explain addition reactions of alkynes

Experiment: Calcium carbide + water reaction. Use sand layer for heat absorption. Collect ethyne over water. Tests: Color, smell, combustion, bromine water, acidified KMnO₄. Safety: Dry apparatus, controlled water addition.
Data analysis: Physical properties of alkynes table. Comparison: Alkynes vs alkenes vs alkanes properties. Worked examples: Combustion reactions of ethyne. Teacher exposition: Two-step addition reactions due to triple bond.

Calcium carbide, Sand, Flat-bottomed flask, Dropping funnel, Gas collection apparatus, Testing solutions
Physical properties charts, Comparison tables, Combustion equation examples
Addition reaction charts, Chemical equation worksheets, Test solutions, Stopwatch for rate comparison

KLB Secondary Chemistry Form 3, Pages 111-112
KLB Secondary Chemistry Form 3, Pages 112-113

ORGANIC CHEMISTRY I

Uses of Alkynes and Industrial Applications

By the end of the lesson, the learner should be able to:
List industrial uses of alkynes
Explain oxy-acetylene welding applications
Describe use in synthetic fiber production
Evaluate importance as chemical starting materials

Discussion: Industrial applications of alkynes in adhesives, plastics, synthetic fibers. Teacher demonstration: Oxy-acetylene flame principles (or video). Q/A: Starting materials for chemical synthesis. Assignment: Research local industrial uses.

Industrial application charts, Welding equipment demonstration/video, Synthetic fiber samples

KLB Secondary Chemistry Form 3, Pages 115-116

SULPHUR AND ITS COMPOUNDS

Extraction of Sulphur
Allotropes of Sulphur

By the end of the lesson, the learner should be able to:
Define sulphur and state its position in the periodic table. Describe the occurrence of sulphur in nature. Explain the Frasch process for extraction of sulphur. Evaluate the effectiveness of the Frasch process.

Q/A: Review group VI elements and electron configuration of sulphur. Teacher demonstration: Using diagrams to explain the Frasch process setup. Discussion: Why ordinary mining is impossible for sulphur deposits. Group work: Students draw and label the Frasch process diagram.

Charts showing periodic table, Diagram of Frasch process, Samples of sulphur compounds (pyrites, gypsum)
Powdered sulphur, Carbon(IV) sulphide, Evaporating dish, Glass rod, Hand lens, Boiling tubes, Filter paper, Beakers

KLB Secondary Chemistry Form 4, Pages 160-161

SULPHUR AND ITS COMPOUNDS

Physical Properties of Sulphur - Solubility
Physical Properties of Sulphur - Effect of Heat
Chemical Properties of Sulphur - Reactions with Elements

By the end of the lesson, the learner should be able to:
Investigate the solubility of sulphur in different solvents. Explain the molecular structure of sulphur. Compare solubility in polar and non-polar solvents. State the physical properties of sulphur.

Practical work: Experiment 2(a) - Testing solubility of sulphur in water, benzene, methylbenzene, and carbon(IV) sulphide. Observation and recording in Table Discussion: Explain why sulphur dissolves in organic solvents but not water. Drawing: Puckered ring structure of S8 molecule.

Powdered sulphur, Water, Benzene, Methylbenzene, Carbon(IV) sulphide, Test tubes, Charts showing molecular structure
Powdered sulphur, Test tubes, Bunsen burner, Cold surface for condensation, Thermometer, Safety equipment
Sulphur, Iron powder, Copper powder, Oxygen gas jar, Deflagrating spoon, Moist litmus papers, Test tubes, Bunsen burner

KLB Secondary Chemistry Form 4, Pages 163-164

SULPHUR AND ITS COMPOUNDS

Chemical Properties of Sulphur - Reactions with Acids
Uses of Sulphur and Introduction to Oxides
Preparation of Sulphur(IV) Oxide
Physical and Chemical Properties of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate the reaction of sulphur with concentrated acids. Identify the products formed in these reactions. Write balanced equations for oxidation reactions. Test for sulphate ions using barium chloride.
Describe laboratory preparation of sulphur(IV) oxide. Set up apparatus for gas preparation and collection. Write balanced equations for the preparation reactions. Explain the drying and collection methods used.

Practical work: Experiment 3(b) - Reactions with concentrated nitric(V) acid, sulphuric(VI) acid, and hydrochloric acid. Testing with barium chloride solution. Observation: Formation of sulphate ions, brown fumes, no reaction with HCl. Discussion: Sulphur as a reducing agent, acids as oxidizing agents.
Practical work: Experiment 4 - Preparation of SO2 using sodium sulphite and dilute HCl. Apparatus setup: Round-bottomed flask, delivery tube, gas jars. Collection: Downward delivery method. Testing: Using acidified potassium chromate(VI) paper. Alternative method: Copper + concentrated H2SO

Sulphur powder, Concentrated HNO3, Concentrated H2SO4, Concentrated HCl, Barium chloride solution, Test tubes, Fume cupboard access
Charts showing uses of sulphur, Samples of vulcanized rubber, Fungicides, Industrial photographs, Textbook diagrams
Sodium sulphite, Dilute HCl, Round-bottomed flask, Delivery tubes, Gas jars, Concentrated H2SO4 for drying, Acidified potassium chromate(VI) paper
SO2 gas from previous preparation, Litmus papers, Universal indicator, 0.1M NaOH solution, Water, Test tubes, Safety equipment

KLB Secondary Chemistry Form 4, Pages 167-168
KLB Secondary Chemistry Form 4, Pages 170-171

SULPHUR AND ITS COMPOUNDS

Bleaching Action of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate the bleaching properties of SO Compare SO2 bleaching with chlorine bleaching. Explain the mechanism of SO2 bleaching. Relate bleaching to paper manufacturing.

Practical work: Experiment 6 - Placing colored flower petals in SO2 gas. Observation: Temporary bleaching effect. Discussion: SO2 + H2O → H2SO3, reduction of organic dyes. Comparison: Permanent vs temporary bleaching. Application: Paper industry bleaching processes.

Colored flower petals (red/blue), SO2 gas jars, Hand lens for observation, Charts comparing bleaching agents

KLB Secondary Chemistry Form 4, Pages 173

SULPHUR AND ITS COMPOUNDS

Reducing Action of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate SO2 as a reducing agent. Test reactions with various oxidizing agents. Write ionic equations for redox reactions. Identify color changes in redox reactions.

Practical work: Experiment 7 - Testing SO2 with acidified potassium dichromate(VI), potassium manganate(VII), bromine water, iron(III) chloride. Recording observations in Table 6. Color changes: Orange to green, purple to colorless, brown to colorless, yellow to pale green. Writing half-equations and overall equations.

SO2 gas, Acidified K2Cr2O7, Acidified KMnO4, Bromine water, Iron(III) chloride solution, Concentrated HNO3, Test tubes

KLB Secondary Chemistry Form 4, Pages 173-176

SULPHUR AND ITS COMPOUNDS

Oxidising Action of Sulphur(IV) Oxide

By the end of the lesson, the learner should be able to:
Investigate SO2 as an oxidizing agent. Demonstrate reaction with stronger reducing agents. Explain the dual nature of SO Write equations for oxidation reactions by SO

Practical work: Experiment 8 - Lowering burning magnesium into SO2 gas. Observation: Continued burning, white fumes of MgO, yellow specks of sulphur. Reaction with hydrogen sulphide gas (demonstration). Discussion: SO2 decomposition providing oxygen. Writing equations: 2Mg + SO2 → 2MgO + S.

SO2 gas jars, Magnesium ribbon, Deflagrating spoon, Hydrogen sulphide gas, Water droppers, Safety equipment

KLB Secondary Chemistry Form 4, Pages 176-177

SULPHUR AND ITS COMPOUNDS

Test for Sulphate and Sulphite Ions & Uses of SO2
Large-scale Manufacture of Sulphuric(VI) Acid - Contact Process
Properties of Concentrated Sulphuric(VI) Acid - Dehydrating Properties

By the end of the lesson, the learner should be able to:
Carry out confirmatory tests for sulphate and sulphite ions. Distinguish between sulphate and sulphite using chemical tests. List the uses of sulphur(IV) oxide. Explain the applications in industry.
Investigate the dehydrating properties of concentrated H2SO Demonstrate removal of water from hydrated salts. Show dehydration of organic compounds. Explain the hygroscopic nature of the acid.

Practical work: Experiment 9 - Testing sodium sulphate and sodium sulphite with barium chloride. Adding dilute HCl to precipitates. Recording observations in Table 8. Discussion: BaSO4 insoluble in acid, BaSO3 dissolves. Uses: Raw material for H2SO4, bleaching wood pulp, fumigant, preservative.
Practical work: Experiment 10 - Adding concentrated H2SO4 to copper(II) sulphate crystals, sucrose crystals, ethanol. Observations: Blue to white crystals, charring of sugar, formation of ethene. Safety: Proper dilution technique - acid to water. Testing evolved gases. Discussion: Chemical vs physical dehydration.

Sodium sulphate solution, Sodium sulphite solution, Barium chloride solution, Dilute HCl, Test tubes, Charts showing industrial uses
Flow chart diagrams, Charts showing industrial plant, Samples of catalyst (V2O5), Photographs of Thika chemical plant, Calculator for percentage calculations
Concentrated H2SO4, Copper(II) sulphate crystals, Sucrose, Ethanol, KMnO4 solution, Test tubes, Beakers, Safety equipment, Fume cupboard

KLB Secondary Chemistry Form 4, Pages 178-179
KLB Secondary Chemistry Form 4, Pages 181-183

SULPHUR AND ITS COMPOUNDS

Properties of Concentrated Sulphuric(VI) Acid - Oxidizing Properties

By the end of the lesson, the learner should be able to:
Investigate the oxidizing properties of concentrated H2SO Test reactions with metals and non-metals. Identify the products of oxidation reactions. Write balanced equations for redox reactions.

Practical work: Experiment 10 (continued) - Reactions with copper foil, zinc granules, charcoal. Testing evolved gases with acidified K2Cr2O7 paper, lime water. Observations: SO2 evolution, color changes. Discussion: H2SO4 → SO2 + H2O + [O]. Writing half-equations and overall equations.

Copper foil, Zinc granules, Charcoal powder, Concentrated H2SO4, Acidified K2Cr2O7 paper, Lime water, Test tubes, Bunsen burner

KLB Secondary Chemistry Form 4, Pages 183-184

SULPHUR AND ITS COMPOUNDS

Properties of Concentrated Sulphuric(VI) Acid - Displacement Reactions

By the end of the lesson, the learner should be able to:
Investigate acid displacement reactions. Demonstrate formation of volatile acids. Test the evolved gases for identification. Write equations for displacement reactions.

Practical work: Experiment 10 (continued) - Reactions with potassium nitrate and sodium chloride. Testing evolved gases with moist blue litmus, concentrated ammonia. Observations: Brown fumes (NO2), white fumes (HCl). Discussion: Less volatile acid displacing more volatile acids. Industrial applications.

Potassium nitrate crystals, Sodium chloride crystals, Concentrated H2SO4, Moist blue litmus paper, Concentrated ammonia, Test tubes, Bunsen burner

KLB Secondary Chemistry Form 4, Pages 184

SULPHUR AND ITS COMPOUNDS

Reactions of Dilute Sulphuric(VI) Acid - With Metals

By the end of the lesson, the learner should be able to:
Investigate reactions of dilute H2SO4 with metals. Compare reactivity of different metals. Test for hydrogen gas evolution. Relate reactions to reactivity series.

Practical work: Experiment 11 - Reactions with magnesium, zinc, copper. Testing evolved gas with burning splint. Recording observations in Table 10. Discussion: More reactive metals above hydrogen displace it. Vigour of reaction decreases down reactivity series. Writing ionic equations.

Magnesium ribbon, Zinc granules, Copper turnings, Dilute H2SO4, Test tubes, Burning splints, Reactivity series chart

KLB Secondary Chemistry Form 4, Pages 184-185

SULPHUR AND ITS COMPOUNDS

Reactions of Dilute Sulphuric(VI) Acid - With Carbonates
Reactions of Dilute Sulphuric(VI) Acid - With Oxides and Hydroxides
Hydrogen Sulphide - Preparation and Physical Properties

By the end of the lesson, the learner should be able to:
Investigate reactions of dilute H2SO4 with carbonates. Test for carbon dioxide evolution. Explain why some reactions stop prematurely. Compare reactions of different metal carbonates.
Describe laboratory preparation of hydrogen sulphide. Set up apparatus for H2S preparation. State the physical properties of H2S. Explain the toxicity and safety precautions.

Practical work: Experiment 12 - Reactions with sodium carbonate, zinc carbonate, calcium carbonate, copper(II) carbonate. Testing evolved gas with lime water. Recording observations in Table 1 Discussion: Formation of insoluble calcium sulphate coating. Effervescence and CO2 identification.
Demonstration: Figure 13 apparatus setup for H2S preparation. Reaction: FeS + 2HCl → FeCl2 + H2S. Collection over warm water due to solubility. Drying: Using anhydrous CaCl2 (not H2SO4). Properties: Colorless, rotten egg smell, poisonous, denser than air. Safety precautions in handling.

Sodium carbonate, Zinc carbonate, Calcium carbonate, Copper(II) carbonate, Dilute H2SO4, Lime water, Test tubes
Metal oxides (MgO, ZnO, CuO, PbO), NaOH solution, 2M H2SO4, Test tubes, Bunsen burner for warming
Iron(II) sulphide, Dilute HCl, Apparatus for gas generation, Anhydrous CaCl2, Gas jars, Safety equipment, Fume cupboard

KLB Secondary Chemistry Form 4, Pages 185-186
KLB Secondary Chemistry Form 4, Pages 187-188

SULPHUR AND ITS COMPOUNDS

Chemical Properties of Hydrogen Sulphide
Pollution Effects and Summary

By the end of the lesson, the learner should be able to:
Investigate H2S as a reducing agent. Test reactions with oxidizing agents. Demonstrate precipitation of metal sulphides. Write ionic equations for redox reactions.

Practical demonstrations: H2S with bromine water, iron(III) chloride, acidified KMnO4, K2Cr2O7. Precipitation tests: H2S with copper(II) sulphate, lead(II) nitrate, zinc sulphate. Color changes: Brown to colorless, yellow to green, purple to colorless. Formation of black, yellow, and white precipitates.

H2S gas, Bromine water, Iron(III) chloride, KMnO4, K2Cr2O7, Metal salt solutions, Test tubes, Droppers
Charts showing pollution effects, Photographs of acid rain damage, Environmental data, Summary charts of reactions, Industrial pollution control diagrams

KLB Secondary Chemistry Form 4, Pages 188-190