NITROGEN AND ITS COMPOUNDS

Introduction to Nitrogen - Properties and Occurrence
Isolation of Nitrogen from Air - Industrial and Laboratory Methods

By the end of the lesson, the learner should be able to:
Describe position of nitrogen in the periodic table
State electron configuration of nitrogen
Identify natural occurrence of nitrogen
Explain why nitrogen exists as diatomic molecules

Teacher exposition: Nitrogen as Group V element, atomic number 7, electron arrangement Discussion: 78% of atmosphere is nitrogen. Q/A: Combined nitrogen in compounds - nitrates, proteins. Explanation: N≡N triple bond strength.

Periodic table charts, Atmospheric composition diagrams, Molecular models showing N≡N triple bond
Aspirator, KOH solution, Copper turnings, Heating apparatus, Fractional distillation flow chart

KLB Secondary Chemistry Form 3, Pages 119

NITROGEN AND ITS COMPOUNDS

Laboratory Preparation of Nitrogen Gas
Properties and Uses of Nitrogen Gas

By the end of the lesson, the learner should be able to:
Prepare nitrogen gas from ammonium compounds
Use sodium nitrite and ammonium chloride method
Test physical and chemical properties of nitrogen
Write equations for nitrogen preparation

Experiment: Mix sodium nitrite (7g) and ammonium chloride ( 5g) with water. Heat gently and collect gas over water. Tests: Color, smell, burning splint, litmus paper, lime water, burning Mg and S. Safety precautions during heating.

Sodium nitrite, Ammonium chloride, Round-bottomed flask, Gas collection apparatus, Test reagents, Deflagrating spoon
Property summary charts, Uses of nitrogen displays, Industrial application diagrams

KLB Secondary Chemistry Form 3, Pages 121-123

NITROGEN AND ITS COMPOUNDS

Nitrogen(I) Oxide - Preparation and Properties

By the end of the lesson, the learner should be able to:
Prepare nitrogen(I) oxide from ammonium nitrate
Test physical and chemical properties
Explain decomposition and oxidizing properties
Describe uses of nitrogen(I) oxide

Experiment: Heat ammonium nitrate carefully in test tube. Collect gas over warm water. Tests: Color, smell, glowing splint test, reaction with heated copper and sulfur. Safety: Stop heating while some solid remains to avoid explosion.

Ammonium nitrate, Test tubes, Gas collection apparatus, Copper turnings, Sulfur, Glowing splints

KLB Secondary Chemistry Form 3, Pages 123-125

NITROGEN AND ITS COMPOUNDS

Nitrogen(II) Oxide - Preparation and Properties
Nitrogen(IV) Oxide - Preparation and Properties
Comparison of Nitrogen Oxides and Environmental Effects

By the end of the lesson, the learner should be able to:
Prepare nitrogen(II) oxide from copper and dilute nitric acid
Observe colorless gas and brown fumes formation
Test reactions with air and iron(II) sulfate
Explain oxidation in air to NO₂
Compare preparation methods of nitrogen oxides
Distinguish between different nitrogen oxides
Explain formation in vehicle engines
Describe environmental pollution effects

Experiment: Add dilute HNO₃ to copper turnings. Observe brown fumes formation then disappearance. Tests: Effect on litmus, burning splint, FeSO₄ complex formation. Discussion: NO oxidation to NO₂ in air.
Comparative study: Properties table of N₂O, NO, NO₂. Discussion: Formation in internal combustion engines. Environmental effects: Acid rain formation, smog, health problems. Worked examples: Distinguishing tests for each oxide.

Copper turnings, Dilute nitric acid, Gas collection apparatus, Iron(II) sulfate solution, Test reagents
Copper turnings, Concentrated nitric acid, Lead(II) nitrate, Gas collection apparatus, U-tube with ice, Testing materials
Comparison charts, Environmental impact diagrams, Vehicle emission illustrations

KLB Secondary Chemistry Form 3, Pages 125-127
KLB Secondary Chemistry Form 3, Pages 123-131

NITROGEN AND ITS COMPOUNDS

Laboratory Preparation of Ammonia
Preparation of Aqueous Ammonia and Solubility

By the end of the lesson, the learner should be able to:
Prepare ammonia from ammonium salts and alkalis
Set up apparatus with proper gas collection
Test characteristic properties of ammonia
Explain displacement reaction principle

Experiment: Heat mixture of calcium hydroxide and ammonium chloride. Collect gas by upward delivery using calcium oxide as drying agent. Tests: Color, smell, combustion, HCl fumes test, litmus paper. Safety: Slanted flask position.

Calcium hydroxide, Ammonium chloride, Round-bottomed flask, Calcium oxide, HCl solution, Glass rod, Litmus paper
Ammonia generation apparatus, Funnel, Universal indicator, Fountain apparatus, pH meter/paper

KLB Secondary Chemistry Form 3, Pages 131-134

NITROGEN AND ITS COMPOUNDS

Reactions of Aqueous Ammonia with Metal Ions
Chemical Properties of Ammonia - Reactions with Acids and Combustion

By the end of the lesson, the learner should be able to:
Test reactions of aqueous ammonia with various metal ions
Observe precipitate formation and dissolution
Explain complex ion formation
Use reactions for metal ion identification

Experiment: Add aqueous ammonia dropwise to solutions of Ca²⁺, Mg²⁺, Al³⁺, Zn²⁺, Fe²⁺, Fe³⁺, Pb²⁺, Cu²⁺. Record observations with few drops vs excess ammonia. Identify complex ion formation with Zn²⁺ and Cu²⁺.

Various metal salt solutions, Aqueous ammonia, Test tubes, Droppers, Observation recording tables
Various dilute acids, Methyl orange, Oxygen supply, Platinum wire, Copper(II) oxide, Combustion apparatus, U-tube for collection

KLB Secondary Chemistry Form 3, Pages 136-138

NITROGEN AND ITS COMPOUNDS

Industrial Manufacture of Ammonia - The Haber Process

By the end of the lesson, the learner should be able to:
Describe raw materials and their sources
Explain optimum conditions for ammonia synthesis
Draw flow diagram of Haber process
Explain economic considerations and catalyst use

Teacher exposition: N₂ from air, H₂ from natural gas/cracking. Process conditions: 500°C, 200 atm, iron catalyst. Flow diagram study: Purification, compression, catalytic chamber, separation, recycling. Economic factors: Compromise between yield and rate.

Haber process flow charts, Industrial diagrams, Catalyst samples, Economic analysis sheets

KLB Secondary Chemistry Form 3, Pages 140-141

NITROGEN AND ITS COMPOUNDS

Uses of Ammonia and Introduction to Nitrogenous Fertilizers
Nitrogenous Fertilizers - Types and Calculations
Laboratory Preparation of Nitric(V) Acid
Industrial Manufacture of Nitric(V) Acid

By the end of the lesson, the learner should be able to:
List major uses of ammonia
Explain importance as fertilizer
Calculate nitrogen percentages in fertilizers
Compare different nitrogenous fertilizers
Prepare nitric acid from nitrate and concentrated sulfuric acid
Set up all-glass apparatus safely
Explain brown fumes and yellow color
Purify nitric acid by air bubbling

Discussion: Uses - fertilizer, refrigerant, cleaning agent, hydrazine production. Introduction to fertilizers: Ammonium sulfate, ammonium nitrate, ammonium phosphate, urea, CAN. Calculations: Percentage nitrogen content in each fertilizer type.
Experiment: Heat mixture of KNO₃ and concentrated H₂SO₄ in all-glass apparatus. Collect yellow nitric acid. Explain brown fumes (NO₂) and yellow color. Bubble air through to remove dissolved NO₂. Safety: Gentle heating, fume cupboard.

Fertilizer samples, Percentage calculation worksheets, Use application charts, Calculator
Various fertilizer formulas, Scientific calculators, Laboratory preparation materials, Environmental impact data
Potassium nitrate, Concentrated sulfuric acid, All-glass apparatus, Condenser, Retort stand, Safety equipment
Industrial process flow charts, Catalyst samples, Process condition charts, Efficiency calculation sheets

KLB Secondary Chemistry Form 3, Pages 141-144
KLB Secondary Chemistry Form 3, Pages 144-145

NITROGEN AND ITS COMPOUNDS

Reactions of Dilute Nitric(V) Acid with Metals

By the end of the lesson, the learner should be able to:
Test reactions with various metals
Explain absence of hydrogen gas production
Observe formation of nitrogen oxides
Write equations for metal-acid reactions

Experiment: Add dilute HNO₃ to Mg, Zn, Cu. Test gases produced with burning splint. Observe that no H₂ is produced (except with Mg in very dilute acid). Explain oxidation of any H₂ formed to water. Record observations and write equations.

Various metals (Mg, Zn, Cu), Dilute nitric acid, Test tubes, Gas testing apparatus, Burning splints

KLB Secondary Chemistry Form 3, Pages 147-150

NITROGEN AND ITS COMPOUNDS

Reactions of Dilute Nitric(V) Acid with Carbonates and Hydroxides
Reactions of Concentrated Nitric(V) Acid - Oxidizing Properties

By the end of the lesson, the learner should be able to:
Test reactions with carbonates and hydrogen carbonates
Test neutralization with metal hydroxides and oxides
Identify products formed
Write balanced chemical equations

Experiments: (a) Add dilute HNO₃ to Na₂CO₃, CaCO₃, ZnCO₃, CuCO₃, NaHCO₃. Test gas evolved with lime water. (b) Neutralize NaOH, CaO, CuO, PbO with dilute HNO₃. Record color changes and write equations.

Various carbonates and hydroxides, Dilute nitric acid, Lime water, Universal indicator, Test tubes
Concentrated nitric acid, Iron(II) sulfate, Sulfur powder, Copper turnings, Test tubes, Fume cupboard access

KLB Secondary Chemistry Form 3, Pages 147-150

NITROGEN AND ITS COMPOUNDS

Uses of Nitric(V) Acid and Introduction to Nitrates

By the end of the lesson, the learner should be able to:
List major industrial uses of nitric acid
Explain importance in fertilizer manufacture
Describe use in explosives and dyes
Introduce nitrate salts and their preparation

Discussion: Uses - fertilizer production (NH₄NO₃), explosives (TNT), dyes, drugs, metal purification, etching. Introduction to nitrates as salts of nitric acid. Methods of preparation: acid + base, acid + carbonate, acid + metal. Examples of common nitrates.

Industrial use charts, Nitrate salt samples, Preparation method diagrams, Safety data sheets

KLB Secondary Chemistry Form 3, Pages 151

NITROGEN AND ITS COMPOUNDS

Action of Heat on Nitrates - Decomposition Patterns
Test for Nitrates - Brown Ring Test
Environmental Pollution by Nitrogen Compounds
Pollution Control and Environmental Solutions

By the end of the lesson, the learner should be able to:
Test thermal decomposition of different nitrates
Classify decomposition patterns based on metal reactivity
Identify products formed on heating
Write equations for decomposition reactions
Explain sources of nitrogen pollution
Describe formation of acid rain
Discuss effects on environment and health
Evaluate pollution control measures

Experiment: Heat KNO₃, NaNO₃, Zn(NO₃)₂, Cu(NO₃)₂, NH₄NO₃ separately. Test gases with glowing splint. Observe residues. Classification: Group I nitrates → nitrite + O₂; Group II → oxide + NO₂ + O₂; NH₄NO₃ → N₂O + H₂O.
Teacher exposition: NOₓ from vehicles, HNO₃ formation in atmosphere, acid rain effects. Discussion: Chlorosis in plants, building corrosion, soil leaching, smog formation, health effects. Control measures: Catalytic converters, emission controls, proper fertilizer use.

Various nitrate salts, Test tubes, Bunsen burner, Gas collection apparatus, Glowing splints, Observation recording sheets
Sodium nitrate, Fresh FeSO₄ solution, Concentrated H₂SO₄, Copper turnings, Test tubes, Unknown nitrate samples
Environmental pollution charts, Acid rain effect photos, Vehicle emission diagrams, Control measure illustrations
Case studies, Pollution control technology information, Group activity worksheets, Local environmental data

KLB Secondary Chemistry Form 3, Pages 151-153
KLB Secondary Chemistry Form 3, Pages 154-157

NITROGEN AND ITS COMPOUNDS

Comprehensive Problem Solving - Nitrogen Chemistry

By the end of the lesson, the learner should be able to:
Solve complex problems involving nitrogen compounds
Apply knowledge to industrial processes
Calculate yields and percentages in reactions
Analyze experimental data and results

Problem-solving session: Mixed calculations involving nitrogen preparation, ammonia synthesis, nitric acid concentration, fertilizer analysis. Industrial application problems. Data analysis from experiments. Integration of all nitrogen chemistry concepts.

Scientific calculators, Comprehensive problem sets, Industrial data sheets, Experimental result tables

KLB Secondary Chemistry Form 3, Pages 119-157

NITROGEN AND ITS COMPOUNDS

Laboratory Practical Assessment - Nitrogen Compounds
Industrial Applications and Economic Importance

By the end of the lesson, the learner should be able to:
Demonstrate practical skills in nitrogen chemistry
Perform qualitative analysis of nitrogen compounds
Apply safety procedures correctly
Interpret experimental observations accurately

Practical examination: Identify unknown nitrogen compounds using chemical tests. Prepare specified nitrogen compounds. Demonstrate proper laboratory techniques. Safety assessment. Written report on observations and conclusions.

Unknown nitrogen compounds, All laboratory chemicals and apparatus used in chapter, Safety equipment, Assessment rubrics
Economic data sheets, Industry case studies, Agricultural statistics, Cost-benefit analysis templates

KLB Secondary Chemistry Form 3, Pages 119-157

NITROGEN AND ITS COMPOUNDS

Chapter Review and Integration

By the end of the lesson, the learner should be able to:
Synthesize all nitrogen chemistry concepts
Compare preparation methods for nitrogen compounds
Relate structure to properties and reactivity
Connect laboratory and industrial processes

Comprehensive review: Concept mapping of all nitrogen compounds and their relationships. Comparison tables: Preparation methods, properties, uses. Flow chart: Nitrogen cycle in industry and environment. Integration exercises connecting all topics.

Concept mapping materials, Comparison charts, Flow diagram templates, Integration worksheets

KLB Secondary Chemistry Form 3, Pages 119-157

THE MOLE

Relative Mass - Introduction and Experimental Investigation
Avogadro's Constant and the Mole Concept
Interconversion of Mass and Moles for Elements
Molecules and Moles - Diatomic Elements

By the end of the lesson, the learner should be able to:
Define relative mass using practical examples
Compare masses of different objects using a reference standard
Explain the concept of relative atomic mass
Identify carbon-12 as the reference standard
Apply the formula: moles = mass/molar mass
Calculate mass from given moles of elements
Convert between moles and number of atoms
Solve numerical problems involving moles and mass

Experiment: Weighing different sized nails using beam balance. Use smallest nail as reference standard. Q/A: Discuss everyday examples of relative measurements. Teacher exposition: Introduction of carbon-12 scale and IUPAC recommendations. Calculate relative masses from experimental data.
Worked examples: Mass-mole conversions using triangle method. Supervised practice: Calculate moles in given masses of common elements. Problem solving: Convert moles to atoms using Avogadro's number. Assignment: Practice problems on interconversion.

Different sized nails ( 5-15cm), Beam balance, Fruits of different masses, Reference charts
Beam balance, Various sized nails, Scientific calculators, Avogadro's constant charts
Scientific calculators, Periodic table, Worked example charts, Formula triangles
Molecular models, Charts showing diatomic elements, Scientific calculators

KLB Secondary Chemistry Form 3, Pages 25-27
KLB Secondary Chemistry Form 3, Pages 30-32

THE MOLE

Empirical Formula - Experimental Determination

By the end of the lesson, the learner should be able to:
Define empirical formula
Determine empirical formula from experimental data
Calculate mole ratios from mass data
Express results as simplest whole number ratios

Experiment: Burning magnesium in air to form magnesium oxide. Measure masses before and after reaction. Calculate moles of Mg and O from mass data. Determine mole ratio and empirical formula. Safety precautions during heating.

Crucible and lid, Magnesium ribbon, Bunsen burner, Beam balance, Tongs, Safety equipment

KLB Secondary Chemistry Form 3, Pages 32-35

THE MOLE

Empirical Formula - Reduction Method
Empirical Formula - Percentage Composition Method

By the end of the lesson, the learner should be able to:
Determine empirical formula using reduction reactions
Calculate empirical formula from reduction data
Apply reduction method to copper oxides
Analyze experimental errors and sources

Experiment: Reduction of copper(II) oxide using laboratory gas. Measure masses before and after reduction. Calculate moles of copper and oxygen. Determine empirical formula from mole ratios. Discuss experimental precautions.

Combustion tube, Porcelain boat, Copper(II) oxide, Laboratory gas, Beam balance, Bunsen burner
Scientific calculators, Percentage composition charts, Worked example displays

KLB Secondary Chemistry Form 3, Pages 35-37

THE MOLE

Molecular Formula - Determination from Empirical Formula
Molecular Formula - Combustion Analysis

By the end of the lesson, the learner should be able to:
Define molecular formula
Relate molecular formula to empirical formula
Calculate molecular formula using molecular mass
Apply the relationship (empirical formula)ₙ = molecular formula

Teacher exposition: Difference between empirical and molecular formulas. Worked examples: Calculate molecular formula from empirical formula and molecular mass. Formula: n = molecular mass/empirical formula mass. Practice problems with various organic compounds.

Scientific calculators, Molecular mass charts, Worked example displays
Scientific calculators, Combustion analysis charts, Molecular models of hydrocarbons

KLB Secondary Chemistry Form 3, Pages 38-40

THE MOLE

Concentration and Molarity of Solutions
Preparation of Molar Solutions
Dilution of Solutions

By the end of the lesson, the learner should be able to:
Define concentration and molarity of solutions
Calculate molarity from mass and volume data
Convert between different concentration units
Apply molarity calculations to various solutions
Describe procedure for preparing molar solutions
Use volumetric flasks correctly
Calculate masses needed for specific molarities
Prepare standard solutions accurately

Teacher exposition: Definition of molarity (moles/dm³). Worked examples: Calculate molarity from mass of solute and volume. Convert between g/dm³ and mol/dm³. Practice problems: Various salt solutions and their molarities.
Experiment: Prepare 1M, 0.5M, and 0.25M NaOH solutions in different volumes. Use volumetric flasks of 1000cm³, 500cm³, and 250cm³. Calculate required masses. Demonstrate proper dissolution and dilution techniques.

Scientific calculators, Molarity charts, Various salt samples for demonstration
Volumetric flasks (250, 500, 1000cm³), Sodium hydroxide pellets, Beam balance, Wash bottles, Beakers
Volumetric flasks, Hydrochloric acid (2M), Measuring cylinders, Pipettes, Safety equipment

KLB Secondary Chemistry Form 3, Pages 41-43
KLB Secondary Chemistry Form 3, Pages 43-46

THE MOLE

Stoichiometry - Experimental Determination of Equations

By the end of the lesson, the learner should be able to:
Determine chemical equations from experimental data
Calculate mole ratios from mass measurements
Write balanced chemical equations
Apply stoichiometry to displacement reactions

Experiment: Iron displacement of copper from CuSO₄ solution. Measure masses of iron used and copper displaced. Calculate mole ratios. Derive balanced chemical equation. Discuss spectator ions.

Iron filings, Copper(II) sulphate solution, Beam balance, Beakers, Filter equipment

KLB Secondary Chemistry Form 3, Pages 50-53

THE MOLE

Stoichiometry - Precipitation Reactions
Stoichiometry - Gas Evolution Reactions

By the end of the lesson, the learner should be able to:
Investigate stoichiometry of precipitation reactions
Determine mole ratios from volume measurements
Write ionic equations for precipitation
Analyze limiting and excess reagents

Experiment: Pb(NO₃)₂ + KI precipitation reaction. Use different volumes to determine stoichiometry. Measure precipitate heights. Plot graphs to find reaction ratios. Identify limiting reagents.

Test tubes, Lead(II) nitrate solution, Potassium iodide solution, Burettes, Ethanol, Rulers
Conical flask, Thistle funnel, Plastic bags, Rubber bands, Sodium carbonate, HCl solution

KLB Secondary Chemistry Form 3, Pages 53-56

THE MOLE

Volumetric Analysis - Introduction and Apparatus
Titration - Acid-Base Neutralization

By the end of the lesson, the learner should be able to:
Define volumetric analysis and titration
Identify and use titration apparatus correctly
Explain functions of pipettes and burettes
Demonstrate proper reading techniques

Practical session: Familiarization with pipettes and burettes. Practice filling and reading burettes accurately. Learn proper meniscus reading. Use pipette fillers safely. Rinse apparatus with appropriate solutions.

Pipettes (10, 20, 25cm³), Burettes (50cm³), Pipette fillers, Conical flasks, Various solutions
Burettes, Pipettes, 0.1M NaOH, 0.1M HCl, Phenolphthalein indicator, Conical flasks

KLB Secondary Chemistry Form 3, Pages 58-59

THE MOLE

Titration - Diprotic Acids
Standardization of Solutions
Back Titration Method

By the end of the lesson, the learner should be able to:
Investigate titrations involving diprotic acids
Determine basicity of acids from titration data
Compare volumes needed for mono- and diprotic acids
Write equations for diprotic acid reactions
Define standardization process
Standardize HCl using Na₂CO₃ as primary standard
Calculate accurate concentrations from titration data
Understand importance of primary standards

Experiment: Titrate 25cm³ of 0.1M NaOH with 0.1M H₂SO₄. Compare volume used with previous HCl titration. Calculate mole ratios. Explain concept of basicity. Introduce dibasic and tribasic acids.
Experiment: Prepare approximately 0.1M HCl and standardize using accurately weighed Na₂CO₃. Use methyl orange indicator. Calculate exact molarity from titration results. Discuss primary standard requirements.

Burettes, Pipettes, 0.1M H₂SO₄, 0.1M NaOH, Phenolphthalein, Basicity reference chart
Anhydrous Na₂CO₃, Approximately 0.1M HCl, Methyl orange, Volumetric flasks, Analytical balance
Metal carbonate sample, 0.5M HCl, 0M NaOH, Phenolphthalein, Conical flasks

KLB Secondary Chemistry Form 3, Pages 62-65
KLB Secondary Chemistry Form 3, Pages 65-67

THE MOLE

Redox Titrations - Principles
Redox Titrations - KMnO₄ Standardization

By the end of the lesson, the learner should be able to:
Explain principles of redox titrations
Identify color changes in redox reactions
Understand self-indicating nature of some redox reactions
Write ionic equations for redox processes

Teacher exposition: Redox titration principles. Demonstrate color changes: MnO₄⁻ (purple) → Mn²⁺ (colorless), Cr₂O₇²⁻ (orange) → Cr³⁺ (green). Discussion: Self-indicating reactions. Write half-equations and overall ionic equations.

Potassium manganate(VII), Potassium dichromate(VI), Iron(II) solutions, Color change charts
Iron(II) ammonium sulfate, KMnO₄ solution, Dilute H₂SO₄, Pipettes, Burettes

KLB Secondary Chemistry Form 3, Pages 68-70

THE MOLE

Water of Crystallization Determination

By the end of the lesson, the learner should be able to:
Determine water of crystallization in hydrated salts
Use redox titration to find formula of hydrated salt
Calculate value of 'n' in crystallization formulas
Apply analytical data to determine complete formulas

Experiment: Determine 'n' in FeSO₄(NH₄)₂SO₄·nH₂O. Dissolve known mass in acid, titrate with standardized KMnO₄. Calculate moles of iron(II), hence complete formula. Compare theoretical and experimental values.

Hydrated iron(II) salt, Standardized KMnO₄, Dilute H₂SO₄, Analytical balance

KLB Secondary Chemistry Form 3, Pages 72-73

THE MOLE

Atomicity and Molar Gas Volume
Combining Volumes of Gases - Experimental Investigation

By the end of the lesson, the learner should be able to:
Define atomicity of gaseous elements
Classify gases as monoatomic, diatomic, or triatomic
Determine molar gas volume experimentally
Calculate gas densities and molar masses

Experiment: Measure volumes and masses of different gases (O₂, CO₂, Cl₂). Calculate densities and molar masses. Determine volume occupied by one mole. Compare values at different conditions.

Gas syringes (50cm³), Various gases, Analytical balance, Gas supply apparatus
Gas syringes, Dry NH₃ generator, Dry HCl generator, Glass connecting tubes, Clips

KLB Secondary Chemistry Form 3, Pages 73-75

THE MOLE
ORGANIC CHEMISTRY I

Gas Laws and Chemical Equations
Introduction to Organic Chemistry and Hydrocarbons
Sources of Alkanes - Natural Gas, Biogas, and Crude Oil

By the end of the lesson, the learner should be able to:
Apply Avogadro's law to chemical reactions
Use volume ratios to determine chemical equations
Calculate product volumes from reactant volumes
Solve problems involving gas stoichiometry
Define organic chemistry and hydrocarbons
Explain why carbon forms many compounds
Classify hydrocarbons into alkanes, alkenes, and alkynes
Identify the bonding in carbon compounds

Worked examples: Use Gay-Lussac's law to determine equations. Calculate volumes of products from given reactant volumes. Apply Avogadro's law to find number of molecules. Practice: Complex gas stoichiometry problems.
Teacher exposition: Definition of organic chemistry. Discussion: Unique properties of carbon - tetravalency, catenation, multiple bonding. Q/A: Examples of hydrocarbons in daily life. Introduction to three main groups of hydrocarbons.

Scientific calculators, Gas law charts, Volume ratio examples
Carbon models, Hydrocarbon structure charts, Molecular model kits
Biogas digester model/diagram, Natural gas composition charts, Organic waste samples

KLB Secondary Chemistry Form 3, Pages 77-79
KLB Secondary Chemistry Form 3, Pages 86-87

ORGANIC CHEMISTRY I

Fractional Distillation of Crude Oil
Cracking of Alkanes - Thermal and Catalytic Methods

By the end of the lesson, the learner should be able to:
Explain fractional distillation process
Perform fractional distillation of crude oil
Identify different fractions and their uses
Relate boiling points to molecular size

Experiment: Fractional distillation of crude oil using improvised column. Collect fractions at different temperatures (120°C intervals up to 350°C). Test fractions for appearance, flammability, and viscosity. Record observations and relate to molecular size.

Crude oil sample, Boiling tubes, High-temperature thermometer, Sand/porcelain chips, Bunsen burner, Test tubes
Cracking process diagrams, Chemical equation charts, Catalyst samples for demonstration

KLB Secondary Chemistry Form 3, Pages 87-89

ORGANIC CHEMISTRY I

Alkane Series and Homologous Series Concept

By the end of the lesson, the learner should be able to:
Define homologous series using alkanes
Write molecular formulas for first 10 alkanes
Identify characteristics of homologous series
Apply general formula CₙH₂ₙ₊₂ for alkanes

Teacher exposition: Homologous series definition and characteristics. Table completion: Names, molecular formulas, and structures of first 10 alkanes. Discussion: General formula application. Pattern recognition: Gradual change in physical properties.

Alkane series chart, Molecular formula worksheets, Periodic table

KLB Secondary Chemistry Form 3, Pages 90-92

ORGANIC CHEMISTRY I

Nomenclature of Alkanes - Straight Chain and Branched
Isomerism in Alkanes - Structural Isomers

By the end of the lesson, the learner should be able to:
Name straight-chain alkanes using IUPAC rules
Identify parent chains in branched alkanes
Name branched alkanes with substituent groups
Apply systematic naming rules correctly

Teacher demonstration: Step-by-step naming of branched alkanes. Rules application: Longest chain identification, numbering from nearest branch, substituent naming. Practice exercises: Various branched alkane structures. Group work: Name complex branched alkanes.

Structural formula charts, IUPAC naming rules poster, Molecular model kits
Molecular model kits, Isomerism charts, Structural formula worksheets

KLB Secondary Chemistry Form 3, Pages 90-92

ORGANIC CHEMISTRY I

Laboratory Preparation of Methane
Laboratory Preparation of Ethane
Physical Properties of Alkanes

By the end of the lesson, the learner should be able to:
Describe laboratory preparation of methane
Perform methane preparation experiment safely
Test physical and chemical properties of methane
Write equation for methane preparation
Prepare ethane using sodium propanoate and soda lime
Compare preparation methods of methane and ethane
Test properties of ethane gas
Write general equation for alkane preparation

Experiment: Heat mixture of sodium ethanoate and soda lime. Collect methane gas over water. Tests: Color, smell, combustion, reaction with bromine in dark. Record observations in table format. Safety precautions during gas collection.
Experiment: Prepare ethane from sodium propanoate and soda lime. Compare with methane preparation method. Carry out similar tests as for methane. Discussion: General pattern for alkane preparation from sodium alkanoates.

Sodium ethanoate, Soda lime, Round-bottomed flask, Gas collection apparatus, Bromine water, Wooden splints
Sodium propanoate, Soda lime, Gas collection apparatus, Testing materials
Physical properties data tables, Graph paper, Calculators, Solubility demonstration materials

KLB Secondary Chemistry Form 3, Pages 94-96

ORGANIC CHEMISTRY I

Chemical Properties of Alkanes - Combustion and Substitution
Uses of Alkanes in Industry and Daily Life

By the end of the lesson, the learner should be able to:
Write equations for complete and incomplete combustion
Explain substitution reactions with halogens
Describe conditions for halogenation reactions
Name halogenated alkane products

Worked examples: Combustion equations for various alkanes. Teacher demonstration: Methane + bromine in sunlight (or simulation). Discussion: Free radical mechanism in substitution. Practice: Write equations for chlorination of methane.

Molecular models, Halogenation reaction charts, Chemical equation worksheets
Industrial application charts, Product samples, Environmental impact materials

KLB Secondary Chemistry Form 3, Pages 97-98

ORGANIC CHEMISTRY I

Introduction to Alkenes and Functional Groups

By the end of the lesson, the learner should be able to:
Define alkenes and unsaturation
Identify the C=C functional group
Write general formula for alkenes (CₙH₂ₙ)
Compare alkenes with alkanes

Teacher exposition: Alkenes definition and unsaturation concept. Introduction: C=C double bond as functional group. Table study: First 6 members of alkene series. Comparison: Alkenes vs alkanes - formulas and structures.

Alkene series charts, Molecular models showing double bonds, Functional group posters

KLB Secondary Chemistry Form 3, Pages 100-101

ORGANIC CHEMISTRY I

Nomenclature of Alkenes
Isomerism in Alkenes - Branching and Positional

By the end of the lesson, the learner should be able to:
Apply IUPAC rules for naming alkenes
Number carbon chains to give lowest numbers to double bonds
Name branched alkenes with substituents
Distinguish position isomers of alkenes

Teacher demonstration: Step-by-step naming of alkenes. Rules application: Longest chain with double bond, numbering from end nearest double bond. Practice exercises: Name various alkene structures. Group work: Complex branched alkenes with substituents.

IUPAC naming charts for alkenes, Structural formula worksheets, Molecular model kits
Molecular model kits, Isomerism worksheets, Geometric isomer models

KLB Secondary Chemistry Form 3, Pages 101-102

ORGANIC CHEMISTRY I

Laboratory Preparation of Ethene
Alternative Preparation of Ethene and Physical Properties
Chemical Properties of Alkenes - Addition Reactions

By the end of the lesson, the learner should be able to:
Prepare ethene by dehydration of ethanol
Describe role of concentrated sulfuric acid
Set up apparatus safely for ethene preparation
Test physical and chemical properties of ethene
Explain addition reactions due to C=C double bond
Write equations for halogenation of alkenes
Describe hydrogenation and hydrohalogenation
Explain addition mechanism

Experiment: Dehydration of ethanol using concentrated H₂SO₄ at 170°C. Use sand bath for controlled heating. Pass gas through NaOH to remove impurities. Tests: Bromine water, acidified KMnO₄, combustion. Safety precautions with concentrated acid.
Teacher exposition: Addition reactions definition and mechanism. Worked examples: Ethene + Cl₂, Br₂, HBr, H₂. Discussion: Markovnikov's rule for unsymmetrical addition. Practice: Various addition reaction equations.

Ethanol, Concentrated H₂SO₄, Round-bottomed flask, Sand bath, Gas collection apparatus, Testing solutions
Aluminum oxide catalyst, Glass wool, Alternative apparatus setup, Physical properties charts
Addition reaction charts, Mechanism diagrams, Chemical equation worksheets

KLB Secondary Chemistry Form 3, Pages 102-104
KLB Secondary Chemistry Form 3, Pages 105-107

ORGANIC CHEMISTRY I

Oxidation Reactions of Alkenes and Polymerization
Tests for Alkenes and Uses

By the end of the lesson, the learner should be able to:
Describe oxidation by KMnO₄ and K₂Cr₂O₇
Explain polymerization of ethene
Define monomers and polymers
Write equations for polymer formation

Demonstration: Decolorization of KMnO₄ by alkenes. Teacher exposition: Polymerization process and polymer formation. Examples: Ethene → polyethene formation. Discussion: Industrial importance of polymerization. Practice: Write polymerization equations.

Oxidizing agents for demonstration, Polymer samples, Polymerization charts, Monomer-polymer models
Test alkenes, Bromine water, Acidified KMnO₄, Plastic samples, Uses reference charts

KLB Secondary Chemistry Form 3, Pages 107-108

ORGANIC CHEMISTRY I

Introduction to Alkynes and Triple Bond

By the end of the lesson, the learner should be able to:
Define alkynes and triple bond structure
Write general formula for alkynes (CₙH₂ₙ₋₂)
Identify first members of alkyne series
Compare degree of unsaturation in hydrocarbons

Teacher exposition: Alkynes definition and C≡C triple bond. Table study: First 6 members of alkyne series with structures. Discussion: Degrees of unsaturation - alkanes vs alkenes vs alkynes. Model demonstration: Triple bond representation.

Alkyne series charts, Triple bond molecular models, Unsaturation comparison charts

KLB Secondary Chemistry Form 3, Pages 109-110

ORGANIC CHEMISTRY I

Nomenclature and Isomerism in Alkynes
Laboratory Preparation of Ethyne

By the end of the lesson, the learner should be able to:
Apply IUPAC naming rules for alkynes
Name branched alkynes with substituents
Draw structural isomers of alkynes
Identify branching and positional isomerism

Teacher demonstration: Systematic naming of alkynes using -yne suffix. Practice exercises: Name various alkyne structures. Drawing exercise: Isomers of pentyne and hexyne. Group work: Complex branched alkynes with multiple substituents.

IUPAC naming rules for alkynes, Structural formula worksheets, Molecular model kits
Calcium carbide, Sand, Flat-bottomed flask, Dropping funnel, Gas collection apparatus, Testing solutions

KLB Secondary Chemistry Form 3, Pages 110-111

ORGANIC CHEMISTRY I

Physical and Chemical Properties of Alkynes
Addition Reactions of Alkynes and Chemical Tests
Uses of Alkynes and Industrial Applications

By the end of the lesson, the learner should be able to:
Describe physical properties of alkynes
Compare alkyne properties with alkenes and alkanes
Write combustion equations for alkynes
Explain addition reactions of alkynes
List industrial uses of alkynes
Explain oxy-acetylene welding applications
Describe use in synthetic fiber production
Evaluate importance as chemical starting materials

Data analysis: Physical properties of alkynes table. Comparison: Alkynes vs alkenes vs alkanes properties. Worked examples: Combustion reactions of ethyne. Teacher exposition: Two-step addition reactions due to triple bond.
Discussion: Industrial applications of alkynes in adhesives, plastics, synthetic fibers. Teacher demonstration: Oxy-acetylene flame principles (or video). Q/A: Starting materials for chemical synthesis. Assignment: Research local industrial uses.

Physical properties charts, Comparison tables, Combustion equation examples
Addition reaction charts, Chemical equation worksheets, Test solutions, Stopwatch for rate comparison
Industrial application charts, Welding equipment demonstration/video, Synthetic fiber samples

KLB Secondary Chemistry Form 3, Pages 112-113
KLB Secondary Chemistry Form 3, Pages 115-116