ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Endothermic and Exothermic Reactions.
Energy level diagrams.

By the end of the lesson, the learner should be able to:






To differentiate between endothermic & exothermic reactions.

Investigate temperature changes in solution formation.

Obtain changes in temperature when ammonium nitrate and sodium hydroxide are dissolved in water, one at a time.

Ammonium nitrate,
Sodium hydroxide, thermometers.
student book

K.L.B. BK IV
Pages 32-33

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy Notation. Change of state.

By the end of the lesson, the learner should be able to:
Define the term enthalpy.
Distinguish positive enthalpy change from negative enthalpy change.

Determine the M.P/ B.P of a pure substance.

Q/A and brief discussion.
Class experiments: determine B.P of pure water/ M.P of naphthalene / ice.
Use experimental results to plot temperature-time graphs.
Explain the shape of the graphs.
Q/A: review kinetic theory of matter.
Apply the theory to explain the shape of the graph, and nature of bonding in substances.

Ice, naphthalene, thermometers, graph papers.

K.L.B. BK IV
Pages 35-39

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

CAT
Molar heat of solution.
Molar heat of solution of H2SO4.

By the end of the lesson, the learner should be able to:

Determine molar heat of solution of H2SO4.

Dissolve some known volume of conc. H2SO4 in a given volume of water.
Note the change in temperature.
Work out the molar heat of solution of H2SO4.

Ammonia nitrate / sodium hydroxide, thermometers.
Conc. H2SO4, thermometers.

K.L.B. BK IV
Pages 42-45

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Enthalpy of combustion. Enthalpy of combustion.

By the end of the lesson, the learner should be able to:
Define the term enthalpy of combustion.
Determine the enthalpy of combustion of ethanol.
Explain why actual heats of combustion are usually lower than the theoretical values.

Group experiments / teacher demonstration.

Obtain and record results.


Work out calculations.

Ethanol, distilled water, thermometer, clear wick, tripod stand and wire gauze.

K.L.B. BK IV
Pages 45-48

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of displacement of ions.

By the end of the lesson, the learner should be able to:
Define the term molar heat of solution of displacement of ions.
Determine the molar heat of solution of displacement of ions.

Group experiments/ teacher demonstration.
Note steady temperature of solutions formed when zinc/ iron / magnesium reacts with copper sulphate solution.
Work out the molar heat of displacement of a substance from a solution of its ions.

Zinc, iron, magnesium, copper sulphate solution.

K.L.B. BK IV
Pages 48-50

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Molar heat of solution of neutralization.
Standard enthalpy changes.

By the end of the lesson, the learner should be able to:
Define the term neutralization.
Determine the molar heat of neutralization of HCl with NaOH.

Class experiments:
Neutralize 2M HCl of known volume with a determined volume of 1M / 2M sodium hydroxide.
Note highest temperature of the solution.
Work out the molar heat of neutralization.
Solve other related problems.
Assignment.

2M HCl of known volume, 1M / 2M sodium hydroxide.
student book

K.L.B. BK IV
Pages 50-53

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Hess?s Law.
Heat of solution hydration energy and lattice energy.

By the end of the lesson, the learner should be able to:
State Hess?s law.

Solve problems related to Hess?s law.
Define the terms lattice energy and hydration energy.
Explain the relationship between heat of solution, hydration energy.
Solve related problems.

Detailed discussion & guided discovery of the law.
Illustrations of energy cycles and energy levels leading to Hess?s law.
Worked examples.
Supervised practice
Written assignment.

Exposition of new concepts.
Guided discovery of the relationship between heat solution hydration energy and lattice energy.
Worked examples.
Assignment.

student book

K.L.B. BK IV
Pages 56-57
K.L.B. BK IV
Pages 60-64

ENERGY CHANGES IN PHYSICAL & CHEMICAL PROCESSES.

Heat values of fuels.
Environmental effects of fuels.

By the end of the lesson, the learner should be able to:
Define the term fuel.
Describe energy changes when a fuel undergoes combustion.
Outline factors considered when choosing a suitable fuel.

Probing questions and brief discussion.

student book

K.L.B. BK IV
Pages 64-66

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of temperature of reactants on rate of reaction.
Effect of change in surface area of reactants on the rate of a reaction.

By the end of the lesson, the learner should be able to:
Explain the effect of temperature on rate of reaction.

Group experiments: investigate the effects of temperature on the rate of reaction of sodium thiosulphate with dilute HCl.
Sketch and interpret relevant graphs.
Discuss the collision theory and effects of activation energy.

Sodium thiosulphate heated at different temperatures, dilute HCl, stopwatches.
Graph papers.
Marble chips, marble chips powder, syringes, conical flasks with stoppers, 1M HCl.

K.L.B. BK IV
Pages 80-83

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of a suitable catalyst on the rate of a reaction
Effect of light on rate of specific reactions.

By the end of the lesson, the learner should be able to:
Explain effects of a suitable catalyst on the rate of a reaction.

Teacher demonstration: preparation and collection of oxygen gas without using a catalyst, then using manganese (IV) oxide as a catalyst.
Explain the results in terms of activation energy.

Hydrogen peroxide, manganese (IV) oxide.
Silver bromide.

K.L.B. BK IV
Pages 85-88

RATES OF REACTION & REVERSIBLE REACTIONS.

Reversible reactions.
State of equilibrium in chemical reactions.
Le Chatelier?s Principle.

By the end of the lesson, the learner should be able to:
Write down equations for reversible reactions.
Define the term equilibrium as used in reversible reactions.
Write down equations of reversible reactions in a state of equilibrium.

Q/A: review temporary and permanent changes.
Teacher demonstration: heating crystals of hydrated copper (II) sulphate, then ?hydrating? them.
Write the corresponding chemical equations.
Give further examples of reversible reactions.


Brief discussion, giving examples of chemical equations for reversible reactions.

Crystals of hydrated copper (II) sulphate.
student book
Add 2M sodium hydroxide,

K.L.B. BK IV
Pages 91-93
K.L.B. BK IV
Pages 94-95

RATES OF REACTION & REVERSIBLE REACTIONS.

Effect of change of pressure and temperature on equilibrium shift.
The Haber Process.

By the end of the lesson, the learner should be able to:
Explain the effect of change of pressure & te,perature on equilibrium shift.

Q/A: review kinetic theory of matter.
Q/A & discussion on effect of change of pressure / temperature on shifting of equilibrium; giving specific examples of chemical equations.
Written assignment.

student book

K.L.B. BK IV
Pages 97-101

RATES OF REACTION & REVERSIBLE REACTIONS.
ELECTRO-CHEMISTRY.

The Contact Process.
Redox reactions.

By the end of the lesson, the learner should be able to:
Explain how change of temperature and pressure affect rate of manufacture of sulphur (VI) acid.

Probing questions and brief discussion.

Assignment.

student book

K.L.B. BK IV
Pages 103-104

ELECTRO-CHEMISTRY.

Oxidizing Numbers.

By the end of the lesson, the learner should be able to:
Outline rules of assigning oxidation numbers.
Determine the oxidation numbers of an element in a given compound.
Explain the use of oxidation numbers in naming compounds.

Exposition and giving specific examples.
Work out oxidizing number of elements in given compounds.
Copy and complete a table of compounds containing elements that more than one oxidation number.

student book

K.L.B. BK IV
Pages 109-116

ELECTRO-CHEMISTRY.

Displacement reactions.
The oxidizing power of an element.
Cell diagrams.
Standard Electrode Potentials.

By the end of the lesson, the learner should be able to:
Explain change of oxidation numbers during redox / displacement reactions. Arrange elements in order of their reducing power.
Define the terms electrode, potential and e.m.f. of an electrochemical cell.
Describe components of a cell diagram.
Draw cell diagrams using correct notations.

Class standard experiments: reacting metals with solutions containing metal ions.
Taking note of reactions and those that do not take place; and tabulating the results.
Teacher demonstration: Zinc/ copper cell.
Q/A & discussion: changes in oxidation numbers.
Exposition: cell diagram and deducing the direction of electron flow.

Metals: Ca, Na, Zn, Fe, Pb, and Cu.
Solutions containing Ca2+, Mg2+, Zn2+, Fe2+.
Halogens:
Cl2 (g),
Br2 (l),
I2 (s).
Halides:
KCl, KBr, KI.
Zinc/ copper cell.
student book

K.L.B. BK IV
Pages 116-120
K.L.B. BK IV
Pages 123-128

ELECTRO-CHEMISTRY.

Standard electrode potential series.

By the end of the lesson, the learner should be able to:
Recall the order of standard electrode potentials.
Compare oxidizing and reducing powers of substances.

Q/A: review reactivity series, oxidizing agent, reducing agent.
Exposition: the order of standard electrode potentials.
Discussion: oxidizing and reducing powers of substances.

student book

K.L.B. BK IV
Pages 131-133

ELECTRO-CHEMISTRY.

Emf of a cell.
Possibility of a reaction to take place.

By the end of the lesson, the learner should be able to:
Calculate emf of a cell using standard electrodes potentials.

Q/A: review half-cells.
Worked examples; supervised practice.
Assignment.

student book

K.L.B. BK IV
Pages 133-136

ELECTRO-CHEMISTRY.

Primary and secondary chemical cells.

By the end of the lesson, the learner should be able to:
Describe the functioning of primary and secondary chemical cells.

Exposition of new concepts and brief discussion
Assignment.

student book

K.L.B. BK IV
Pages 138-141

ELECTRO-CHEMISTRY.

Electrolysis of dilute NaCl.
Electrolysis of brine.
Electrolysis of dilute sulphuric (VI) acid.

By the end of the lesson, the learner should be able to:
Define the term electrolysis.
Explain the concept of preferential discharge of ions.
Identify products of electrolysis of dilute sulphuric (VI) acid.

Teacher demonstration: electrolysis of dilute sodium chloride with carbon electrodes.
Test for gases collected.
Write down equations of reactions at each electrode.
Discussion: preferential discharge of ions at electrodes.

Teacher demonstration/ group experiments.
Test for the products of electrolysis.
Write relevant equations.

Dilute sodium chloride voltameter.
Brine voltameter.
Sulphuric acid voltameter.

K.L.B. BK IV
Pages 141-144
K.L.B. BK IV
Pages 146-148

ELECTRO-CHEMISTRY.

Factors affecting electrolysis.
Application of electrolysis.

By the end of the lesson, the learner should be able to:
Explain factors that affect electrolytic products discharged at electrodes.

Q/A: review the electrochemical series of elements.
Teacher writes down order of ease of discharge of ions at electrodes.
Discussion: other factors; giving suitable examples.

student book
Suitable voltameter.

K.L.B. BK IV
Pages 153-5

ELECTRO-CHEMISTRY.
METALS

Faraday?s law of electrolysis.
Ores of some metals.

By the end of the lesson, the learner should be able to:
State Faraday?s law of electrolysis.
Solve problems related to Faraday?s law of electrolysis.

Discuss above results, leading to Faraday?s law of electrolysis.

Worked examples.

Assignment.

Weighing balance, stop watch, copper sulphate voltameter.

K.L.B. BK IV
Pages 161-4

METALS

Occurrence and extraction of sodium.
Occurrence and extraction of aluminium.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of sodium.

Oral questions on electrolysis and equations at electrodes.
Brief discussion on occurrence and extraction.

Chart: Down?s cell.
student book

K.L.B. BK IV
Pages 170-171

METALS

Occurrence and extraction of iron.
Occurrence and extraction of zinc.
Extraction of lead.

By the end of the lesson, the learner should be able to:
Describe occurrence and extraction of iron.
Describe occurrence and extraction of zinc by electrolysis and reduction methods.

Brief discussion.
Write relevant chemical equations.

Chart: Blast furnace.
Flow chart: extraction of Zinc.
Flow chart: extraction of lead.

K.L.B. BK IV
Pages 173-5
K.L.B. BK IV
Pages 175-9

METALS

Occurrence and extraction of copper.
Physical properties of some metals.

By the end of the lesson, the learner should be able to:
Describe extraction of copper.

Q/A & brief discussion.
Write balanced chemical equations leading to extraction of copper.

Flow chart: extraction of copper.
student book

K.L.B. BK IV
Pages 181-183

METALS

Reaction of metals with oxygen.

By the end of the lesson, the learner should be able to:
Explain effect of burning metals in air.

Teacher demonstration / Group experiments.
Burning some metals in air.
Write relevant equations.
Brief discussion.

Common lab. metals.

K.L.B. BK IV
Pages 184-6

METALS

Reaction of metals with cold water and steam.

By the end of the lesson, the learner should be able to:
Describe reaction of metals with cold water and steam.

Arrange the metals in order of reactivity with cold water and steam.

Class experiments:
Investigate reaction of some metals with cold water and steam.
Analyse the results.

Metals: Al, Zn, Fe, Cu.

K.L.B. BK IV
Pages 186-9

METALS

Reaction of metals with chlorine.
Reaction of metals with acids.
Uses of metals.

By the end of the lesson, the learner should be able to:
Describe the reaction of metals with chlorine.
Describe and explain reaction of metals with acids.

Teacher demonstration in a fume cupboard / in the open.
Investigate reaction of metals with chorine
Write corresponding equations.


Group experiments: investigate reaction of metals with dilute acids.
Teacher demonstration: investigate reaction of metals with concentrated acids.
Discuss the observations made and write relevant chemical equations.

Metals: Al, Zn, Fe, Cu.
Metals: Al, Zn, Fe, Cu.
Acids; HCl, HNO3, H2SO4.
student book

K.L.B. BK IV
Pages 189-191
K.L.B. BK IV
Pages 191-4

METALS
ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Environmental effects of extraction of metals.
Alkanols (Alcohols).

By the end of the lesson, the learner should be able to:
Identify some environmental effects of extraction of metals.

Oral questions and open discussion.

Assignment / Topic review.

student book

K.L.B. BK IV
Pages 197-8

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Nomenclature of alkanols.

By the end of the lesson, the learner should be able to:
Name and draw the structure of simple alkanols.

Guided discovery of naming system for alkanols.
Draw and name structures of alkanols.

student book

K.L.B. BK IV
Pages 206-8

ORGANIC CHEMISTRY II (ALKANES & ALKANOIC ACIDS)

Isomerism in alkanols.
Preparation of ethanol in the lab.

By the end of the lesson, the learner should be able to:
Describe positional and chain isomerism in alkanols.
Explain formation of primary and secondary alkanols.

Q/A: review the terms positional and chain isomerism.
Brief discussion on isomerism.
Oral exercise: naming given organic compounds.
Written exercise: writing structural formulae for isomers of organic compounds of a given molecular formula.

student book
Calcium hydroxide solution, sugar solution, yeast.

K.L.B. BK IV
Pages 208-10

RADIOACTIVITY

Definition of radioactivity.
Alpha particles.
Equations involving alpha particles.
Beta particles. Gamma rays.
Radioactive Half-Life.

By the end of the lesson, the learner should be able to:


Define radioactivity, a nuclide and radioactive decay.
Differentiate between natural and artificial radioactivity.


State properties of alpha particles.
Describe methods of detecting alpha particles.

Q/A: Review the atomic structure.
Exposition: symbolic representation of an atom / nucleus.
Exposition: meaning of radioactivity and radioactive decay.
Discussion: artificial and natural radioactivity.


Q/A: position of helium in the periodic table.

Expository approach:

student book
student book
Dice.

K.L.B. BK IV
Pages 249-251
K.L.B. BK IV
Pages 251-253

RADIOACTIVITY

Radioactive decay curve.
Nuclear fusion and nuclear fission. Applications of radioactivity.

By the end of the lesson, the learner should be able to:
Plot a radioactive decay curve to deduce the
half ?life from the curve.

Drawing a radioactive decay curve inferring the half-life of the sample from the graph.

Graph papers.
student book

K.L.B. BK IV
Pages 254-5